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загрузка. пожалуйста, подождите... make your home | add to favorites log in логин: password ( forgot? ): another's computer log in check in llc "ukrspetsoliva" home check in contact details feedback русская версия українська версія сортировать статьи по: дате | популярности | посещаемости | комментариям | алфавиту enterprise llc "ukrspetsoliva" autho: admin от 5-10-2015, 02:22 enterprise llc "ukrspetsoliva" was founded in 2004 to produce emulsifiers, used to produce return emulsions and started producing the product in june 2006. our products are mainly used in mining industry to make emulsion explosives (ee). enterprise llc "ukrspetsoliva" is located in ukraine, in the city of kryvyi rih. not only do we produce the material, but, if needed, we deliver the products to our clients. enterprise llc "ukrspetsoliva" produces emulsifiers (surface active agents) under commercial names special oils "emol" of grade a, b, according to ukrainian standards туу 23.2-33264625-001:2005, that are used to produce emulsion explosives. using of ee is economically beneficial and provides explosive works with minimum contamination of the environment. our consumers are the biggest producers of ee in ukraine. we reached optimal ratio of price to quality for the manufactured products. the basis of the production is our scientific developments that made it possible to create a surface active agent (emulsifier) that meets the demands in the industry concerning production of industrial emulsive explosives. we developed formulation and technology to receive emulsifiers at big scale and also organized designing of the plant for their synthesis. the enterprise develops new emulsifiers in order to extend fields of usage of ee including conditions of underground. we adjust properties of emulsifiers for the conditions of work and types of raw materials of specific consumers. enterprise llc "ukrspetsoliva" is ready for cooperation to implement the existing oils "emol" of grade a, b, c and to develop surface active agents with the properties the customers need. read more 1529 category: information widening the range of emulsive explosive application autho: admin от 8-02-2016, 19:05 34 1 2 3 4 5 the article describes the properties of waterless molten emulsions of ammonium, calcium and sodium nitrate mixtures in industrial oils including their physical properties, thermal resistance, combustion and detonation. there presented the ap-plication technology to be used in mining and the corresponding equipment characteristics. the problem and its connection with research and practical tasks. in the first us patent for the emulsion explosive “water-in-oil” [1] the water content in the explosive makes up 15 – 35%. the water does not undergo any reactions ensuring the heat emission in blasting and is a ballast decreasing the blasting efficiency. the evident way of increasing specific blast energy is to decrease the water content in the emulsion explosive. for instance, some patents offer the water content of 14 – 17% [2] or 10 – 12% [3]. research and publication analysis. the aim of increasing the specific energy can be achieved by introducing high-energy oxidizing agents like chlorates and perchlorates, individual explosives like hexogen, ten (pentaerythrite tetranitrate), monomethylamine nitrate or high-energy combustibles – aluminum and magnesium. the examples of such compounds can be found in the patent [4]. here the water content makes up 5-12%. the compound also consists of monomethylamine nitrate and sodium perchlorate. it is offered to incorporate perchlorates, the water content making 14-20% [5]. the water content decrease causes the accelerated crystallization of the emulsion on cooling accompanied by the change in properties of explosives and the water resistance decrease. thus, such solidifying emulsions are also of some interest and, as the authors think, are able to replace tnt and pentolite blocks [6]. these emulsions crystallize a short time after cooling. the water content in the offered compounds is up to 5%. in [7] some similar compounds of the crystallized emulsions with the water content of 5% are described, but with a special addition of crystallizing nuclei for solidification acceleration. the problem of obtaining the emulsion with low water content and no crystallization can be solved by incorporating some substances preventing the crystal growth in the nitrate solution [8]. the water content is 8-18%. waterless emulsions are described in [9]. they can be called “melt-in-oil emulsion”. in some cases of the test-pieces carbamide, ammonium formate, sodium formate or ammonium acetate are used as water substitutes for decreasing the melting temperature. all these compounds contain oxygen, which is part of the organic substance and does not take part in blasting reactions accompanied by heat emission. the compound based on the mixture of ammonium nitrate and silver nitrate (19%) is the only compound of the suggested waterless compounds on the molten nitric acid salts without additional low-melt components. problem statement. the research aims at obtaining resistant waterless “melt-in-oil” emulsions on the basis of ammoniac, sodium and calcium nitrates and investigating their properties with possible application in blasting. material presentation and results. the enterprise llc “ukrspetsoliva” developed an emulsifier, which enables to produce emulsions for emulsion explosives without water. the emulsions include an emulsifier, combustible components such as industrial oils as well as ammoniac, sodium and calcium nitrates. strictly speaking, the emulsions described below, contain water. the water quantity depends on its content in the primary components. thus, for example, a prilled ammonium nitrate defined in the standard gost 2-85 contains 0.3% of water. therefore, the water content in emulsion is on the same level, but such quantity is not usually taken into account in engineering designs. the properties of such emulsions differ from the properties of emulsions applied for producing wet emulsion explosives. on the basis of such waterless emulsions with the indicated components one can obtain explosives with the blasting heat of more than 3800 kilojoule/kg and the amount of gaseous explosion products of about 850 l/kg. the density of emulsion test-pieces under˚ the temperature of +20˚ degrees made up 1470 – 1480 kg/m3. as for the indicated characteristics, the given emulsions can be compared to trotyl [10]. this fact makes it possible to produce boosters or priming cartridges according to the principle that a primer should have more considerable explosive characteristics (blasting heat, density, detonation velocity) than the initiated charge. speaking about physical properties, we can mention hygroscopicity of waterless emulsions. if kept outside with the relative air humidity of 30%, the emulsion has a film containing water. it has quite different properties from those of the primary emulsion. emulsions are characterized by certain water-resistance conditioned by the formation of the mentioned film insoluble in water. thermal stability of emulsions thermal stability tests were conducted for the emulsion test-pieces of 100ml. the compounds were incubated in oil baths under the temperature of +160˚ celsius over a period of up to 6 hours. the visual appearance change of the emulsions was observed. two hours later the compounds with carbamide additions under the temperature of +130˚ expand due to the gas emission. we should admit that the emulsion expansion does not occur at once, but with two-hour delay. under the temperature of 140˚, the expansion begins in 1.5 hours. it is observed [11] that carbamide decelerates the ammoniac nitrate decomposition. however, the tests of the emulsions containing no carbamide revealed their greater thermal stability. they can withstand thermostating with the temperature of +160˚ during 6 hours without any changes in appearance. we suggest th

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